18. First Example of the μ3-η1,η2,η1-C60 Bonding Mode: Ligand-Induced Conversion of π to σ C60–Metal Complexes

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author H. Song, K. Lee, C. H. Lee, J. T. Park, H. Y. Chang, and M. G. Choi
journal Angew. Chem. Int. Ed., 2001, 40, 1500
link http://onlinelibrary.wiley.com/doi/10.10...O;2-W/full


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A boat-shaped 1,4-cyclohexadiene-like ring is present in the C60 molecule with a novel σ-typeμ3-η1,η2,η1 bonding mode in the clusters 2 a and 2 b. The change in coordination mode was induced by insertion of an RNC ligand into an Os−Os bond of the π-type C60 complex 1. R=CH2C6H5.



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