093. Novel Polymer Nanowire Crystals of Diketopyrrolopyrrole-Based Copolymer with Excellent Charge Transport Properties

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author J. H. Kim, D. H. Lee, D. S. Yang, D. U. Heo, K. H. Kim, J. Shin, H. -J. Kim, K.-Y. Baek, K. Lee, H. Baik, M. J. Cho, D. H. Choi
journal Adv. Mater., 2013, 25, 4102
Link http://onlinelibrary.wiley.com/doi/10.10...6/abstract
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The first demonstration of polymer nanowire (PNW) crystals based on a diketopyrrolopyrrole-based copolymer (i.e., PDTTDPP), and their application to field-effect transistors (FETs) is reported. Remarkably, transmission electron microscopy and selected area electron diffraction analyses of the PNW reveal its single-crystalline (SC) nature. FETs fabricated of a SC PNW exhibit a maximal charge carrier mobility of ≈7.00 cm2 V−1 s−1, which is almost one order of magnitude higher than that of the thin-film transistors made of the same polymer (PDTTDPP).


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